Using the X102 gas evolution setup, Matxain, Freixa, Huertos et al. observed an unprecedented high H/D kinetic isotope effect in catalytic silane hydrolysis, uncovering a key role for hydrogen tunneling in the reaction mechanism.
Using the X102 gas evolution setup, Matxain, Freixa, Huertos et al. observed an unprecedented high H/D kinetic isotope effect in catalytic silane hydrolysis, uncovering a key role for hydrogen tunneling in the reaction mechanism.